Main Group Chemistry @ IISERTVM
@MainTvm
We are Synthetic Chemists Interested in the Structure and Reactivity of Main Group Compounds.
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Now online in @NatureSynthesis Synthesis and reactivity of an antimony(III) dication doi.org/10.1038/s44160… This work is in collaboration with Laurent Maron We are thankful for @ANRFIndia for funding & @tvmiiser @Chemie_iisertvm for the facilities. @Deepti__Sharma…
Like weird metal clusters? Our latest work shows an unprecedented "open" Sb8 cluster, out now as a HOT article in the Main Group issue of @InorgChemFront! Congrats to MSc student Mitch on his 1st first auth paper! cc @chemistryatuvic @DalhousieU Chemistry pubs.rsc.org/en/content/art…
Have a look our recent article on Nickel-Catalyzed Dehydrogenative Zn–Zn Coupling to a Zn(I) Dimer and Its Reactivity - now published in Chemical Communications pubs.rsc.org/en/content/art… Congratulations to Sagrika💐 @ANRFIndia @niser_official @ChemCommun
In this @J_A_C_S paper, we harness the synergistic interplay of thiols and thio/selenocarbonyls to achieve the two-electron reduction of nitrite to HNO at zinc(II). Thanks @ANRFIndia for CRG/2021 grant. pubs.acs.org/doi/full/10.10…
I’m thrilled to share that I’ve successfully defended my thesis! 🎓✨ My heartfelt thanks to my supervisor, Prof. Ajay Venugopal @MainTvm, for his unwavering guidance, support, and inspiration throughout this journey. Onward to new beginnings! 🚀
New group photo of the #maingroup team @tvmiiser! Looking forward to soon sharing some amazing works from these young, energetic, yet patient guys!
Thesis Defence by Mr. Suban Kundu, from Prof. Ajay Venugopal's group. @tvmiiser
Thesis Defence by Ms. Sheetal Kathayat Bisht, from Prof. Ajay Venugopal's group. @tvmiiser
Two high-quality PhD theses by @skathayat27 and @suban_kundu are up for defense back-to-back. Many thanks to @Coles_lab @GoicoecheaGroup @SharanNembenna @PtlabIISc for reviewing the theses.
Crystal Structure of the Ammine Complex [Ca(C2H)2(NH3)4] (Uwe Ruschewitz and co-workers) • onlinelibrary.wiley.com/doi/10.1002/za…
![ZAAC_Journal's tweet card. Needle-shaped crystals of [Ca(C2H)2(NH3)4] were obtained by reacting elemental calcium dissolved in liquid ammonia with acetylene and slowly evaporating the former. X-ray single crystal structure...](https://pbs.twimg.com/card_img/1992905201766768640/hwJIGsTQ?format=jpg&name=orig)
A simple reductant-controlled approach to Sulfinamides from Amines via formal SO insertion to C-N bond — now published in @JOC_OL (@ACSPublications )! 🔬 Thanks to @CSIR_IND for the financial support !!! @Chemie_iisertvm @tvmiiser pubs.acs.org/doi/full/10.10…
Excited to share the work of @AndrewPlatten4 @DCBPunibern in collaboration with #LauraTorrenteMurciano @cebcambridge introducing the use of #SodiumAmides in #DES in #continuousFlow for ester amidations #SustainableSynthesis #OpenAccess @ACSPublications pubs.acs.org/doi/pdf/10.102…
Freedom, programming and arts – Odile Eisenstein on her favourite things to do and some helpful words of advice. chemistryworld.com/opinion/odile-…
Have a look at our recent article on "Magnesium Catalyzed Hydroamination of Carbodiimide and Hydroboration of Cyanamides" - now published in Dalton Transactions (this time NacnacMg hydride Catalysis) pubs.rsc.org/en/content/art… @ANRFIndia @niser_official
Thrilled to share the work of @clarencetankl and @antorna on elevating #sodium mediated deprotonative #borylation to #catalytic regimes with an insightful #mechanistic study in collaboration with @MGarcia_Melchor @acsJACS pubs.acs.org/doi/10.1021/ja…
We have developed a Rapid & Accelerated Biodegradation (RAB) of Bioplastic, in a simple way, funded by DBT & thanks to Dr BALENDRA SINGH, for the support @DBTIndia @BalendraSingh3 @RoySocChem - now published in Materials Advances pubs.rsc.org/en/content/art…
PhD positions in MAIN GROUP CHEMISTRY for UGC/CSIR-JRF scholarship holder @tvmiiser. maingroupchemistrylab.com Application Deadline: 8th November 2025 Application Portal: admissions.iisertvm.ac.in/phd/index.php/…
Have a look our recent work on Magnesium Catalysis, i.e., Bis-Guanidinate Magnesium Amide-Catalyzed Hydroboration of Nitriles and Isocyanides via a Substrate Assisted Pathway - now published in Organic Chemistry Frontiers : pubs.rsc.org/en/content/art… @ANRFIndia @niser_official
Organoantimony: a versatile main-group platform for pnictogen-bonding and redox catalysis pubs.rsc.org/en/content/art…
🎓 PhD Opportunity @TheSahooGroup @tvmiiser Join cutting-edge research in catalysis for Sustainable Organic Synthesis 🧪 Eligible: UGC/CSIR-JRF holders 🔗 Portal:admissions.iisertvm.ac.in/phd/index.php/…
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