Imogen S
@imo_squire
PhD student at KCL | Main group chemistry | Organometallic | Uni of York alumna | she/her
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A hexavalent nickel complex! Reductive addition of three Be-Be bonds at Ni(0) produces Ni(BeCp)6. @GroupAldridge pubs.acs.org/doi/10.1021/ja…
I’m delighted our collaborative work with @StephanieJUrwin @cowley_group has been published in @EurJIC ! Here are some fun new alkyl-Mg complexes with tuneable phosphaamidinate ligands that show lactide ROP activity: …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ej… @EdinburghChem @GardenGroupChem
Researchers synthesised Ph4Pn by oxidising Mg[Ph4Pn] with one equivalent of iodine, which created a MgI2 precipitate within minutes. chemistryworld.com/news/antiaroma…
Check out Dhara's (@DharaChem) work on the catenation of aluminium, now out in @J_A_C_S Thanks to @felipefantuzzi and all the coauthors! pubs.acs.org/doi/10.1021/ja… #chemtwitter #UniWue
📢 We have a PhD position available in our lab exploring main group compounds and their reactivity. We are very happy for people to contact us with informal enquires! kcl.ac.uk/study-legacy/f….
In case you missed it: 'Probing the reactivity of a transient Al(i) species with substituted arenes' by Clare Bakewell, first author Imogen Squire and co. from @bakewellgroup #OpenAccess 🔓 pubs.rsc.org/en/content/art…
📢𝗦𝗰𝗵𝗹𝗲𝗻𝗸 𝗟𝗶𝗻𝗲 𝗖𝗼𝗺𝗺𝘂𝗻𝗶𝘁𝘆 𝗦𝘂𝗿𝘃𝗲𝘆📢 I am running a survey to understand Schlenk line design preferences and to gather information about techniques/training. Please do take some time to complete the survey and share with others! smartsurvey.co.uk/s/Schlenk/
Imogen’s work investigating a transient Al(I) species is now available online as an accepted article in @ChemCommun - supported by Mickey and some serendipitous crystal growing by Juliana. Congratulations @imo_squire 💥 pubs.rsc.org/en/content/art…
Delighted to share my work on a singly bonded gallanediyl, which is able to undergo carbometalation reactions with alkynes by retention of the +I oxidation state. nature.com/articles/s4416…
Now in full dress and included in the latest issue of @ChemicalScience: The understanding and tuning of pentalenides 🧠🎚 ☺🎉. For more than 60 years unthinkable, one of my thesis chapters introduced flexible designing & tuning to this ligand. 📣 1/x 🧵 pubs.rsc.org/en/content/art…
New @ChemRxiv from Marina Perez-Jimenez and @RoesslerGroup is now out. It describes the isolation, characterisation, and electronic structure of a Paramagnetic Nickel-Zinc Hydride Complex, along with hints that such species may be relevant in catalysis. chemrxiv.org/engage/chemrxi…
Very cool work by @InoueGroupTUM in @angew_chem on P₄ reduction by base-stabilised dialumenes and onward functionalisation to give phosphines! onlinelibrary.wiley.com/doi/10.1002/an…
Nice to see this work is out from my PhD group! Was always a big fan of recycling our BDI ligands (cus I could never be bothered to synthesise fresh batches 😅) Good work @dong_huanhuan and everyone else!
A just accepted paper in @DaltonTrans from work in the #Stasch group developing new diketiminate ligands and complexes, and with twelve structures from the service. Congrats to Connor, @dong_huanhuan, Katharine and Lena. DOI doi.org/10.1039/D4DT01… @StAndrewsChem
We've polarized the Be-Be bond! Our latest investigations into low-oxidation state beryllium chemistry have just been published in @NatureChemistry. @GroupAldridge @OxfordChemistry nature.com/articles/s4155…
Two PhD applications now open to come and work in the Bakewell group! Come and join us - we're a friendly bunch and are excited to welcome new members to the lab! Clare is a great supervisor and these projects are an opportunity to work on some very cool main group chemistry 🧪👩🔬
We have two exciting PhD opportunities available in our group working in the field of main group chemistry - both are open to UK and international applicants 🌍 Please email me to organise informal discussions about the projects. Retweets appreciated 🔁 findaphd.com/phds/project/e…
I am happy to share that our paper on the first heterobimetallic dimetallocene is finally published in @NatureChemistry! nature.com/articles/s4155… Thank you to everyone who contributed, most importantly Inga Bischoff, who did the experimental work, as well as @ICCGroup2 @Tetidanes!
Do you identify as "electrocurious"? Here's a list of helpful reviews I found when I was starting out with electrochemistry. By no means a complete list of everything out there, but these were some of my most accessed and cover a very broad range of topics (1/10)
Season 2 of @periodically_ox launches today. Episode 1 has a really thoughtful discussion of endometriosis, touching on the themes of chronic illness and the ambiguous employee/student situation of a PhD candidate ([how] can you take sick leave?).
EPISODE 1: ENDOMETRIOSIS OUT NOW! Available to listen wherever you get your podcasts or via the link below! linktr.ee/periodically_ox ❤️🩸🧪 #endometriosis
Delighted to see our perspective article on C-H and C-F bond activation of fluoroarenes highlighted in @ChemicalScience as one of the most popular inorganic chemistry articles from last year! @Ale_and_Co_ @EvaHeviaGroup pubs.rsc.org/en/content/art…
Announcing our most popular article collections for 2023 📣 These special collections have been curated by our editorial team to showcase some of the most popular articles published in Chemical Science last year. For more details see our blog: blogs.rsc.org/sc/2024/04/25/…
Really cool work by @chloejohnsoon and the rest of the team!
SMOM-Gold! @chloejohnsoon's just accepted @angew_chem, with @MacgregorChem @CamposGroup @miquelnb. Sequential single-crystal solid/gas reactivity to make a Au-acetylene complex. Synthesis, bonding , VT Xray, & NMR (check out the 13C-labelled NMR spectrum) tinyurl.com/5yemfyht
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