#peroxygenase search results
A Chemoenzymatic Cascade for the Formal Enantioselective Hydroxylation and Amination of Benzylic C−H Bonds; Y. Zhang, C. Huang, W. Kong, L. Zhou, J. Gao, F. Hollmann, Y. Liu, & Yanjun Jiang #singleatomcatalysts #peroxygenase #enantioselective doi.org/10.1021/acscat…
A. Pothuizen, R. I. Wouters, H. Brasselet, T. Hilberath, Y. Wu & F. Hollmann; From characterization to biocatalytic application of two peroxygenases from Collariella virescens and Daldinia caldariorum #Peroxygenase #Oxidation #Epoxidation doi.org/10.5802/crchim…
Toward Kilogram-Scale Peroxygenase-Catalyzed Oxyfunctionalization of Cyclohexane; T. Hilberath, R. van Oosten, J. Victoria @Hugo_Brslt @MiguelAlcaldeG J. M. Woodley & F. Hollmann #biocatalysis #peroxygenase #oxyfunctionalization #cyclohexane #upscaling doi.org/10.1021/acs.op…
pubs.acs.org
Toward Kilogram-Scale Peroxygenase-Catalyzed Oxyfunctionalization of Cyclohexane
Mol-scale oxyfunctionalization of cyclohexane to cyclohexanol/cyclohexanone (KA-oil) using an unspecific peroxygenase is reported. Using AaeUPO from Agrocybe aegerita and simple H2O2 as an oxidant,...
Assessing Peroxygenase-Mediated Oxidations in the Presence of High Concentrations of Water-Miscible Co-Solvents; Th. Hilberath, A. van Troost, M. Alcalde & @Hollmann_TUD #peroxygenase #oxyfunctionalization #epoxidation engineeringhttps://doi.org/10.3389/fctls.2022.882992
Y. Wu @Caroline_E_Paul T. Hilberath, E. P. J. Jongkind,[a] W. Zhang @MiguelAlcaldeG & Frank Hollmann @MiguelAlcaldeG #fattyacidvalorisation #peroxygenase #multienzymecascades #selectiveoxyfunctionalisation doi.org/10.1002/cctc.2…
chemistry-europe.onlinelibrary.wiley.com
Peroxygenase‐Promoted Enzymatic Cascades for the Valorisation of Fatty Acids
Multi-enzyme cascade: Peroxygenases enable facile functionalisation of fatty acids. The resulting hydroxy fatty acids can be further derivatised to new building blocks for chemical synthesis.
Congrats to our Laura Rotilio for the new paper on Unspecific #Peroxygenase, Prof. Mattevi lab www-9.unipv.it/biocry/, @DBB_UniPV, @unipv pubs.acs.org/doi/10.1021/ac…
pubs.acs.org
Structural and Biochemical Studies Enlighten the Unspecific Peroxygenase from Hypoxylon sp. EC38 as...
Unspecific peroxygenases (UPOs) are glycosylated fungal enzymes that can selectively oxidize C–H bonds. UPOs employ hydrogen peroxide as the oxygen donor and reductant. With such an easy-to-handle...
Selective Peroxygenase-Catalysed Oxidation of Phenols to Hydroquinones; @Hugo_Brslta F. Schmitz, K. Koschorreck, V. B. Urlacher, F. Hollmann & @THilberath #Biocatalysis #Peroxygenase #Oxyfunctionalisation #Phenols #Hydroquinones doi.org/10.1002/adsc.2…
A Novel Unspecific Peroxygenase from Galatian marginata for Biocatalytic Oxyfunctionalization Reactions; Y. Ma, H. Liang, Z. Zhao, B. Wu, D. Lan, @Hollmann_TUD Y. Wang #peroxygenase #Galerinamarginata #Bioinformaticsanalysis #Oxyfunctionalization doi.org/10.1016/j.mcat…
great work by @chrismheckmann in @Caroline_E_Paul lab: #Peroxygenase-Catalyzed Allylic Oxidation Unlocks Telescoped #Synthesis of (1S,3R)-3-Hydroxycyclohexanecarbonitrile | in @ACSCatalysis pubs.acs.org/doi/10.1021/ac…
Peroxygenase-Catalysed Selective Oxidation of Silanes to Silanols; X. Xu, J. M. A. van Hengst, Y. Mao, M. Martinez, S. Roda, M. Floor, V. Guallar @Caroline_E_Paul @MiguelAlcaldeG & F. Hollmann #Biocatalysis #Oxyfunctionalization #Peroxygenase #Silanols doi.org/10.1002/anie.2…
NaturalDeepEutecticSolventsasPerformanceAdditivesforPeroxygenaseCatalysis; coauthored by @Hollmann_TUD @SCUT_SIE @LeidenBiology @kh_univ @ProtEngin #eutecticsolvents #biocatalysis #Peroxygenase DOI:10.1002/cctc.201901842
Selective Peroxygenase-Catalysed Oxidation of Toluene Derivates to Benzaldehydes; Y. Wang, N. Teetz, @DirkHoltmann @MiguelAlcaldeG J. M.A. van Hengst, X. Liu, M. Wang, W. Qi, W. Zhang, F. Hollmann #Benzaldehydes #Biocatalyticoxidation #Peroxygenase doi.org/10.1002/cctc.2…
chemistry-europe.onlinelibrary.wiley.com
Selective Peroxygenase‐Catalysed Oxidation of Toluene Derivates to Benzaldehydes
The peroxygenase from Agrocybe aegerita highly selectively converts substituted toluene derivates into the corresponding aldehydes. Using the immobilised enzyme enables non-aqueous reaction conditi...
An alginate-confined peroxygenase-CLEA for styrene epoxidation; F. E. H. Nintzel, Y. Wu, @plank89 M. Held, M. Alcalde and @Hollmann_TUD @csic #Oxyfunctionalisation #biocatalysis #peroxygenase #CLEA #enantioselective #epoxidation pubs.rsc.org/en/content/art…
H2 as a fuel for flavin- and H2O2-dependent biocatalytic reactions; A. Al-Shameri, S. J.-P. Willot, @Caroline_E_Paul, @Hollmann_TUD @LarsLauterbach #Flavinmononucleotide #flavinadeninedinucleotide #peroxygenase #hydrogenases pubs.rsc.org/en/content/art…
Piezobiocatalysis: Ultrasound-Driven Enzymatic Oxyfunctionalization of C−H Bonds J. Yoon, J. Kim, F. Tieves, W. Zhang, M. Alcalde, @Hollmann_TUD and C. Beum Park @KAIST_CBE @CSIC #oxidation #oxyfunctionalization #peroxygenase, #piezobiocatalysis doi.org/10.1021/acscat…
Natural deep eutectic solvents #DES as additives for #peroxygenase #catalysis from South China University of Technology, @tudelft, Austrian Centre for Industrial Biotechnology, @UniLeidenNews, @kh_univ and @CSIC doi.wiley.com/10.1002/cctc.2…
Plasma‐Driven in Situ Production of Hydrogen Peroxide for Biocatalysis; A. Yayci, Á. G. Baraibar, M. Krewing, E. Fernandez Fueyo, @Hollmann_TUD , M. Alcalde, R. Kourist, J. E. Bandow @ruhrunibochum @tugraz #biocatalysis #peroxidase #peroxygenase doi.org/10.1002/cssc.2…
chemistry-europe.onlinelibrary.wiley.com
Plasma‐Driven in Situ Production of Hydrogen Peroxide for Biocatalysis
Ride the lightning: Non-thermal plasma is applied for noninvasive production of hydrogen peroxide to be used in biocatalysis. Side effects of plasma exposure can be alleviated by enzyme immobilizat...
Enabling Peroxygenase Activity in Cytochrome P450 Monooxygenases by Engineering Hydrogen Peroxide Tunnels @CHNSci #Biocatalysis #Peroxygenase #Cytochrome #P450 #Monooxygenases #HydrogenPeroxide #Tunnels pubs.acs.org/doi/10.1021/ja…
A. Pothuizen, R. I. Wouters, H. Brasselet, T. Hilberath, Y. Wu & F. Hollmann; From characterization to biocatalytic application of two peroxygenases from Collariella virescens and Daldinia caldariorum #Peroxygenase #Oxidation #Epoxidation doi.org/10.5802/crchim…
A Chemoenzymatic Cascade for the Formal Enantioselective Hydroxylation and Amination of Benzylic C−H Bonds; Y. Zhang, C. Huang, W. Kong, L. Zhou, J. Gao, F. Hollmann, Y. Liu, & Yanjun Jiang #singleatomcatalysts #peroxygenase #enantioselective doi.org/10.1021/acscat…
Selective Peroxygenase-Catalysed Oxidation of Phenols to Hydroquinones; @Hugo_Brslt F. Schmitz, K. Koschorreck, V. B. Urlacher, F. Hollmann & @Th_Hilberath #Biocatalysis #Peroxygenase #Oxyfunctionalisation #Phenols #Hydroquinones doi.org/10.1002/adsc.2…
Selective Peroxygenase-Catalysed Oxidation of Phenols to Hydroquinones; @Hugo_Brslta F. Schmitz, K. Koschorreck, V. B. Urlacher, F. Hollmann & @THilberath #Biocatalysis #Peroxygenase #Oxyfunctionalisation #Phenols #Hydroquinones doi.org/10.1002/adsc.2…
great work by @chrismheckmann in @Caroline_E_Paul lab: #Peroxygenase-Catalyzed Allylic Oxidation Unlocks Telescoped #Synthesis of (1S,3R)-3-Hydroxycyclohexanecarbonitrile | in @ACSCatalysis pubs.acs.org/doi/10.1021/ac…
Toward Kilogram-Scale Peroxygenase-Catalyzed Oxyfunctionalization of Cyclohexane; T. Hilberath, R. van Oosten, J. Victoria @Hugo_Brslt @MiguelAlcaldeG J. M. Woodley & F. Hollmann #biocatalysis #peroxygenase #oxyfunctionalization #cyclohexane #upscaling doi.org/10.1021/acs.op…
pubs.acs.org
Toward Kilogram-Scale Peroxygenase-Catalyzed Oxyfunctionalization of Cyclohexane
Mol-scale oxyfunctionalization of cyclohexane to cyclohexanol/cyclohexanone (KA-oil) using an unspecific peroxygenase is reported. Using AaeUPO from Agrocybe aegerita and simple H2O2 as an oxidant,...
Selective Peroxygenase-Catalysed Oxidation of Toluene Derivates to Benzaldehydes; Y. Wang, N. Teetz, @DirkHoltmann @MiguelAlcaldeG J. M.A. van Hengst, X. Liu, M. Wang, W. Qi, W. Zhang, F. Hollmann #Benzaldehydes #Biocatalyticoxidation #Peroxygenase doi.org/10.1002/cctc.2…
chemistry-europe.onlinelibrary.wiley.com
Selective Peroxygenase‐Catalysed Oxidation of Toluene Derivates to Benzaldehydes
The peroxygenase from Agrocybe aegerita highly selectively converts substituted toluene derivates into the corresponding aldehydes. Using the immobilised enzyme enables non-aqueous reaction conditi...
Y. Wu @Caroline_E_Paul T. Hilberath, E. P. J. Jongkind,[a] W. Zhang @MiguelAlcaldeG & Frank Hollmann @MiguelAlcaldeG #fattyacidvalorisation #peroxygenase #multienzymecascades #selectiveoxyfunctionalisation doi.org/10.1002/cctc.2…
chemistry-europe.onlinelibrary.wiley.com
Peroxygenase‐Promoted Enzymatic Cascades for the Valorisation of Fatty Acids
Multi-enzyme cascade: Peroxygenases enable facile functionalisation of fatty acids. The resulting hydroxy fatty acids can be further derivatised to new building blocks for chemical synthesis.
Peroxygenase-Catalysed Selective Oxidation of Silanes to Silanols; X. Xu, J. M. A. van Hengst, Y. Mao, M. Martinez, S. Roda, M. Floor, V. Guallar @Caroline_E_Paul @MiguelAlcaldeG & F. Hollmann #Biocatalysis #Oxyfunctionalization #Peroxygenase #Silanols doi.org/10.1002/anie.2…
Enabling Peroxygenase Activity in Cytochrome P450 Monooxygenases by Engineering Hydrogen Peroxide Tunnels @CHNSci #Biocatalysis #Peroxygenase #Cytochrome #P450 #Monooxygenases #HydrogenPeroxide #Tunnels pubs.acs.org/doi/10.1021/ja…
pubs.acs.org
Enabling Peroxygenase Activity in Cytochrome P450 Monooxygenases by Engineering Hydrogen Peroxide...
Given prominent physicochemical similarities between H2O2 and water, we report a new strategy for promoting the peroxygenase activity of P450 enzymes by engineering their water tunnels to facilitate...
A Novel Unspecific Peroxygenase from Galatian marginata for Biocatalytic Oxyfunctionalization Reactions; Y. Ma, H. Liang, Z. Zhao, B. Wu, D. Lan, @Hollmann_TUD Y. Wang #peroxygenase #Galerinamarginata #Bioinformaticsanalysis #Oxyfunctionalization doi.org/10.1016/j.mcat…
Assessing Peroxygenase-Mediated Oxidations in the Presence of High Concentrations of Water-Miscible Co-Solvents; Th. Hilberath, A. van Troost, M. Alcalde & @Hollmann_TUD #peroxygenase #oxyfunctionalization #epoxidation engineeringhttps://doi.org/10.3389/fctls.2022.882992
Congrats to our Laura Rotilio for the new paper on Unspecific #Peroxygenase, Prof. Mattevi lab www-9.unipv.it/biocry/, @DBB_UniPV, @unipv pubs.acs.org/doi/10.1021/ac…
pubs.acs.org
Structural and Biochemical Studies Enlighten the Unspecific Peroxygenase from Hypoxylon sp. EC38 as...
Unspecific peroxygenases (UPOs) are glycosylated fungal enzymes that can selectively oxidize C–H bonds. UPOs employ hydrogen peroxide as the oxygen donor and reductant. With such an easy-to-handle...
H2 as a fuel for flavin- and H2O2-dependent biocatalytic reactions; A. Al-Shameri, S. J.-P. Willot, @Caroline_E_Paul, @Hollmann_TUD @LarsLauterbach #Flavinmononucleotide #flavinadeninedinucleotide #peroxygenase #hydrogenases pubs.rsc.org/en/content/art…
Piezobiocatalysis: Ultrasound-Driven Enzymatic Oxyfunctionalization of C−H Bonds J. Yoon, J. Kim, F. Tieves, W. Zhang, M. Alcalde, @Hollmann_TUD and C. Beum Park @KAIST_CBE @CSIC #oxidation #oxyfunctionalization #peroxygenase, #piezobiocatalysis doi.org/10.1021/acscat…
Natural deep eutectic solvents #DES as additives for #peroxygenase #catalysis from South China University of Technology, @tudelft, Austrian Centre for Industrial Biotechnology, @UniLeidenNews, @kh_univ and @CSIC doi.wiley.com/10.1002/cctc.2…
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