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Carbon may be the central element of organic chemistry but, for the broader chemical world, oxygen is the element of truly universal importance. Learn more about the many mysteries of this "doubly magical element" from our new book! @ChemistryFsu @FSUartssciences @FloridaState
New in #ChemSci: RIng expansion with ozone + O-nucleophile turns cycloalkenes into medium-ring 1,2-dioxacycloalkanes: introduction of up to five O-atoms at a C=C moiety. Cyclic constraints+stereoelectronics = selective rearrangements. doi:10.1039/D5SC06768E
Every catalyst is a paradox: it must change to make chemistry happen—yet finish unchanged, like a phoenix from the fire. But what if catalysts evolve? What if multiple species coexist? That’s not a bug—it can be a feature that unlocks new pathways.
#NewPaperAlert 📕Cocktail of Catalysts: A Dynamic Advance in Modern Catalysis (by Prof. Mikhail P. Egorov and Prof. Igor V. Alabugin @IAlabugin et al.) mdpi.com/2624-8549/7/4/… #CocktailTypeCatalysis #DynamicCatalysis #MetalNanoparticles #CatalystInterconversion
🎉The 𝐂𝐡𝐞𝐦𝐢𝐬𝐭𝐫𝐲 𝐓𝐫𝐚𝐯𝐞𝐥 𝐀𝐰𝐚𝐫𝐝 is looking for its next winner. 🏆𝐖𝐡𝐚𝐭 𝐭𝐡𝐞 𝐰𝐢𝐧𝐧𝐞𝐫 𝐫𝐞𝐜𝐞𝐢𝐯𝐞𝐬: – CHF 800 – An electronic certificate 📅 Deadline: 𝟑𝟏 𝐃𝐞𝐜𝐞𝐦𝐛𝐞𝐫 𝟐𝟎𝟐𝟓 🔗Application Portal mdpi.com/journal/chemis…
Fans of Corey–Chaykovsky reaction know ylides can stand in for carbenes in cyclopropanations. But can an ylide do C–C bond insertion first? We show the first example: methylene insertion into a C–C bond, then cyclopropanation/epoxidation: pubs.rsc.org/en/content/art…
New study “Lost Data in Electron Microscopy” from @AnanikovLab finds that >97% EM images acquired in a decade remain unpublished: only ~2–3% make it into papers. This is a huge untapped data reservoir for AI and more efficient science! @Chemistry_MDPI mdpi.com/2624-8549/7/5/…
Can ground state reactions borrow stabilization from excited states to proceed faster? A very interesting paper by @JudyWuChem and Rainer Herges!
Now in @J_A_C_S. Sharing Francisco’s new work on modulating the thermal isomerization mechanisms of photoswitching azoarenes. pubs.acs.org/doi/full/10.10…
"Each gram of MOF soaks up 1000 mg of PFOA ...." - the last issue of C&E News makes you think. What is larger "1 g" or "1000 mg"? I hope that you know the answer!
New review in Chemistry: Cocktail-type catalysis challenges the old homogeneous vs. heterogeneous divide. Catalysts can evolve as complexes, clusters & nanoparticles in dynamic equilibrium. Embracing this concept opens new paths for reaction design. 🔗 doi.org/10.3390/chemis…
What a cool NMR spectrum! In addition to the negative chemical shift, note how the stereochemical arrangement of H and P strongly influences the coupling constants.
New personal record for lowest 1H NMR shift on a compound I made. (S/O Inorg Syn for being the goat)
In chemistry, unexpected results should never be wasted — they’re clues, puzzles, and sometimes the start of something new. Accidentally, this one also looks like a great undergrad exam problem
#NewPaperAlert 📕Transformation of Linear Alkenyl N-Alkoxy Carbamates into Cyclic Bromo Carbonates (by Dr. Shyam Sathyamoorthi et al.) mdpi.com/2624-8549/7/3/… #Heterocycles #Alkenes #Bromination #Carbonates #TetheredFunctionalization
Big thanks to the organizers of #AnnumXIII for a highly engaging meeting! Nearly 200 presentations, impressive enthusiasm, and the artistic & research talents of @IPBogor students on full display. It was so contagious that all participants joined!
Proud to say our latest paper just dropped in Accounts of Chemical Research—and it’s an ACS Editors’ Choice! 🎉 We use alkyne benzannulations to make chiral + achiral nanographenes and GNRs in an efficient way. pubs.acs.org/doi/10.1021/ac… #ChemTwitter #Nanographenes @ACSPublications
Prof. Lik Tong Tan asks an intriguing question at #ANNUMXIII: What functional group was identified as a common structural element in a family of natural products based on these NMR spectra? A little puzzle for those who love NMR and physical organic chemistry!
Big thanks to @hanifnovriyandi and everyone at @IPBogor for a wonderful day! Great to meet enthusiastic students and to share exciting research & career opportunities through the @ChemistryFsu graduate program!
Winter can come in August — all you have to do is cross the equator 🌍 #SouthernHemisphere
It seems that Belgian lace makers may be also quite good in making graphene nanostructures
Looking forward to the first full day of photochemistry at Aachen. The morning session starts with talk by Michael Wasielewski. I am sure that it will take audience for a spin! #ICP2025
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