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Chao Li Lab

@LabChao

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Chao Li Lab
 @LabChao
Oct 7

Our Chem. Soc. Rev. Article! Radical Retrosynthesis: A Powerful Strategy for Modern Assembly of Terpenoid Natural Products. Modern radical chemistry—MHAT, RAE, XEC, photoredox, HAT—reshapes retrosynthetic logic for complex terpenoids. pubs.rsc.org/en/content/art…

LabChao's tweet card. Radical retrosynthesis has emerged as a powerful strategy for the modern assembly of complex natural products, offering a one-electron logic that complements traditional polar disconnections. This...
Radical retrosynthesis: a powerful strategy for modern assembly of terpenoid natural products
Source: pubs.rsc.org
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Chao Li Lab
 @LabChao
Feb 5

Thrilled to share our progress on the synthesis of highly oxidized DMOA-derived meroterpenoids—now out in JACS:pubs.acs.org/doi/10.1021/ja…! The unexpected reaction we stumbled upon in the final step turned out to be especially fascinating.

LabChao's tweet card. The synthesis of complex natural products requires efficient control over chemoselectivity, stereoselectivity, and regioselectivity. Berkeleyacetals, a subfamily of 3,5-dimethylorsellinic acid...
Total Synthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Ber...
Source: pubs.acs.org
TotalSynthesis's profile picture. @SoufianTibouti thinks Nature is the ultimate chemist.
Total Synthesis
@TotalSynthesis
Feb 4

#TotalSynthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I by Jianpeng Zhang, Xiaotong Luo, Jingfu Zhang, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…

TotalSynthesis's tweet image. #TotalSynthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I by Jianpeng Zhang, Xiaotong Luo, Jingfu Zhang, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I by Jianpeng Zhang, Xiaotong Luo, Jingfu Zhang, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I by Jianpeng Zhang, Xiaotong Luo, Jingfu Zhang, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of DMOA-Derived Meroterpenoids: Achieving Selectivity in the Synthesis of (+)-Berkeleyacetal D and (+)-Peniciacetal I by Jianpeng Zhang, Xiaotong Luo, Jingfu Zhang, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
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Angewandte Chemie
 @angew_chem
Nov 7, 2024

Establishing the Comprehensive Structure-Activity Relationship of the Natural Antibiotic Kibdelomycin/Amycolamicin (Chao Li and co-workers) @LabChao onlinelibrary.wiley.com/doi/10.1002/an…

angew_chem's tweet card. Through extensive chemical synthesis, the first comprehensive structure–activity relationship (SAR) analysis of the potent natural antibiotics kibdelomycin (KBD) and amycolamicin (AMM) was establis...
Establishing the Comprehensive Structure−Activity Relationship of the Natural Antibiotic Kibdelom...
Source: onlinelibrary.wiley.com
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Chao Li Lab
 @LabChao
Oct 2, 2024

We're excited to have achieved a structure-activity relationship analysis of the complex natural antibiotics Kibdelomycin/Amycolamicin through total synthesis. We hope this work will contribute to the development of new antibiotic therapies. onlinelibrary.wiley.com/doi/10.1002/an…

LabChao's tweet image. We're excited to have achieved a structure-activity relationship analysis of the complex natural antibiotics Kibdelomycin/Amycolamicin through total synthesis. We hope this work will contribute to the development of new antibiotic therapies. onlinelibrary.wiley.com/doi/10.1002/an…
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Baran Lab
@BaranLabReads
Sep 20, 2023

The final version of this study was published today in @Nature : nature.com/articles/s4158…

BaranLabReads's profile picture. Electrifying chemistry...
Baran Lab
@BaranLabReads
Jan 19, 2023

Today we report in @ChemRxiv a scalable solution to the total synthesis (and structural reassignment) of the Portimines (bit.ly/3iJ61DT). In collaboration with @_chrisgparker_ and Luke Lairson the remarkable biological activity of this natural product family was revealed

BaranLabReads's tweet image. Today we report in @ChemRxiv a scalable solution to the total synthesis (and structural reassignment) of the Portimines (bit.ly/3iJ61DT). In collaboration with @_chrisgparker_ and Luke Lairson the remarkable biological activity of this natural product family was revealed
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Yandong Zhang
 @YandongZhang16
Aug 11, 2023

Excited to share our latest paper on the total synthesis of Illicium sesquiterpenes. Not only access more targets but synthetically connect distinct molecular architectures of different subfamilies through late-stage skeletal reorganization triggered by Lewis acids or oxidants.

J_A_C_S's profile picture. Research, news, and information from the Journal of the American Chemical Society.
J. Am. Chem. Soc.
 @J_A_C_S
Aug 11, 2023

Divergent Total Syntheses of Illicium Sesquiterpenes through Late-Stage Skeletal Reorganization | Journal of the American Chemical Society @CHNSci @TotalSynthesis @TotalSyntheses #Divergent #TotalSynthesis #sesquiterpenes #Rearrangement #LateStage pubs.acs.org/doi/10.1021/ja…

pubs.acs.org

Divergent Total Syntheses of Illicium Sesquiterpenes through Late-Stage Skeletal Reorganization

We disclose unified, protecting-group-free, bioinspired divergent total syntheses of eight allo-cedrane and seco-prezizaane Illicium sesquiterpenes and formal syntheses of five anislactone sesquite...

Source: pubs.acs.org
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Angewandte Chemie
 @angew_chem
May 18, 2023

Nickel-Catalyzed C-I-Selective C(sp2)-C(sp3) Cross-Electrophile Coupling of Bromo(iodo)arenes with Alkyl Bromides (Chao Li and co-workers) @LabChao onlinelibrary.wiley.com/doi/10.1002/an…

angew_chem's tweet image. Nickel-Catalyzed C-I-Selective C(sp2)-C(sp3) Cross-Electrophile Coupling of Bromo(iodo)arenes with Alkyl Bromides (Chao Li and co-workers) @LabChao onlinelibrary.wiley.com/doi/10.1002/an…
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LabChao's profile picture.
Chao Li Lab
 @LabChao
May 8, 2023

Hopefully, this recent work from our group will help some medicinal chemists. A general C(sp2)–I selective C(sp2)–C(sp3) cross-electrophile coupling. onlinelibrary.wiley.com/doi/10.1002/an…

LabChao's tweet image. Hopefully, this recent work from our group will help some medicinal chemists. A general C(sp2)–I selective C(sp2)–C(sp3) cross-electrophile coupling. onlinelibrary.wiley.com/doi/10.1002/an…
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Baran Lab
@BaranLabReads
Apr 6, 2023

Modern alchemy appearing today in @ScienceMagazine : science.org/doi/10.1126/sc… Commentary (thank you Prof. Ye!): science.org/doi/10.1126/sc…

BaranLabReads's profile picture. Electrifying chemistry...
Baran Lab
@BaranLabReads
Oct 27, 2022

Modern Alchemy with rAP. Appearing today in @ChemRxiv is a solution to the longstanding (>100 year) challenge of extending the scope of the original Kolbe reaction beyond simple hydrocarbons bearing no functional groups: bit.ly/3sBQ5Ve

BaranLabReads's tweet image. Modern Alchemy with rAP. Appearing today in @ChemRxiv is a solution to the longstanding (>100 year) challenge of extending the scope of the original Kolbe reaction beyond simple hydrocarbons bearing no functional groups: bit.ly/3sBQ5Ve
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Chao Li Lab reposted
BaranLabReads's profile picture.
Baran Lab
@BaranLabReads
Jan 19, 2023

Today we report in @ChemRxiv a scalable solution to the total synthesis (and structural reassignment) of the Portimines (bit.ly/3iJ61DT). In collaboration with @_chrisgparker_ and Luke Lairson the remarkable biological activity of this natural product family was revealed

BaranLabReads's tweet image. Today we report in @ChemRxiv a scalable solution to the total synthesis (and structural reassignment) of the Portimines (bit.ly/3iJ61DT). In collaboration with @_chrisgparker_ and Luke Lairson the remarkable biological activity of this natural product family was revealed
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Chao Li Lab reposted
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Scripps Research
@scrippsresearch
Sep 21, 2022

Congratulations to chemist Prof. Phil Baran, who has been awarded the 2022 Danisco Foundation Science Excellence Award from @IFF. Baran is recognized for advancing science and technology relevant to the future of food, nutrition, and health magazine.scripps.edu/awards-and-hon… @BaranLabReads

scrippsresearch's tweet image. Congratulations to chemist Prof. Phil Baran, who has been awarded the 2022 Danisco Foundation Science Excellence Award from @IFF. Baran is recognized for advancing science and technology relevant to the future of food, nutrition, and health magazine.scripps.edu/awards-and-hon… @BaranLabReads
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Chao Li Lab reposted
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Baran Lab
@BaranLabReads
Sep 15, 2022

Final version of this study was published today in @J_A_C_S : bit.ly/3QGPDhP

BaranLabReads's profile picture. Electrifying chemistry...
Baran Lab
@BaranLabReads
May 27, 2022

Simple, practical, and broadly applicable. Next generation decarboxylative arylation, appearing today in @ChemRxiv : bit.ly/3z6Ko5Y

BaranLabReads's tweet image. Simple, practical, and broadly applicable. Next generation decarboxylative arylation, appearing today in @ChemRxiv : bit.ly/3z6Ko5Y
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Lives in Chemistry
@livesinchem
Aug 10, 2022

🎁Do you recognize this PhD student in front of his hood in 1999? There he started out to become a true artist in @TotalSynthesis. Birthday present: autobio of S. Kent l-i-c.org/1129, the artist of Total Synthesis of #Peptides/#Proteins & #NativeChemicalLigation. Cheers!

livesinchem's tweet image. 🎁Do you recognize this PhD student in front of his hood in 1999? There he started out to become a true artist in @TotalSynthesis. Birthday present: autobio of S. Kent l-i-c.org/1129, the artist of Total Synthesis of #Peptides/#Proteins & #NativeChemicalLigation. Cheers!
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Chao Li Lab reposted
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Baran Lab
@BaranLabReads
Jun 1, 2022

An atroposelective synthesis of Darobactin, appearing today in @ChemRxiv : bit.ly/3z9tJyC

BaranLabReads's tweet image. An atroposelective synthesis of Darobactin, appearing today in @ChemRxiv : bit.ly/3z9tJyC
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Baran Lab
@BaranLabReads
Feb 7, 2022

Electroaffinity labeling: a powerful new tool for target identification and Chemical Biology. Appearing today in @ChemRxiv, a collaboration with brilliant @Merck scientists: bit.ly/3B5eSEv

BaranLabReads's tweet image. Electroaffinity labeling: a powerful new tool for target identification and Chemical Biology. Appearing today in @ChemRxiv, a collaboration with brilliant @Merck scientists: bit.ly/3B5eSEv
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Waser Group
 @LcsoLab
Feb 4, 2022

#LCSOSynthesisProblem of the week! Elija challenged us with the synthesis of Amycolamicin and Kibdelomycin from @LabChao in @J_A_C_S ! #Totalsynthesis Take a look: epfl.ch/labs/lcso/wp-c… For original paper: pubs.acs.org/doi/pdf/10.102…

LcsoLab's tweet image. #LCSOSynthesisProblem of the week! Elija challenged us with the synthesis of Amycolamicin and Kibdelomycin from @LabChao in @J_A_C_S ! #Totalsynthesis Take a look: epfl.ch/labs/lcso/wp-c… For original paper: pubs.acs.org/doi/pdf/10.102…
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Chao Li Lab
 @LabChao
Dec 28, 2021

I am very glad to discover some new TEMPO chemistry in natural product synthesis!

TotalSynthesis's profile picture. @SoufianTibouti thinks Nature is the ultimate chemist.
Total Synthesis
@TotalSynthesis
Dec 28, 2021

Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids by Junming Zhuo, Chunlin Zhu, Jinbao Wu, Zijian Li, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…

TotalSynthesis's tweet image. Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids by Junming Zhuo, Chunlin Zhu, Jinbao Wu, Zijian Li, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids by Junming Zhuo, Chunlin Zhu, Jinbao Wu, Zijian Li, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids by Junming Zhuo, Chunlin Zhu, Jinbao Wu, Zijian Li, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. Reductive Radical Annulation Strategy toward Bicyclo[3.2.1]octanes: Synthesis of ent-Kaurane and Beyerane Diterpenoids by Junming Zhuo, Chunlin Zhu, Jinbao Wu, Zijian Li, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
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Total Synthesis
@TotalSynthesis
Dec 9, 2021

#TotalSynthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin by Shaoqiang Yang, Chenglong Chen, Jie Chen, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…

TotalSynthesis's tweet image. #TotalSynthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin by Shaoqiang Yang, Chenglong Chen, Jie Chen, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin by Shaoqiang Yang, Chenglong Chen, Jie Chen, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin by Shaoqiang Yang, Chenglong Chen, Jie Chen, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
TotalSynthesis's tweet image. #TotalSynthesis of the Potent and Broad-Spectrum Antibiotics Amycolamicin and Kibdelomycin by Shaoqiang Yang, Chenglong Chen, Jie Chen, and Chao Li @LabChao in @J_A_C_S pubs.acs.org/doi/10.1021/ja…
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Gabriele Laudadio

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Ruyi Zhu

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Yu Wang

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cenke

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Dongmin Xu

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Rob Lavigne

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Mauro Mato

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Joel Smith

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Yuxuan Ye

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Zengwei Luo

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XianbiaoFu's profile picture. Asst. Prof. of NUS MSE. TR35. MSCA PF. MRSC. 催化开天地主编. Ammonia synthesis, Electrocatalysis, Electrosynthesis. NUS⬅️DTU⬅️JHU⬅️Northwestern⬅️UESTC⬅️CSU.

Xianbiao Fu (付先彪）

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Liang Chen

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Fa-Guang Zhang

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fuir1

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JIAJING TAN GROUP

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Minghao Feng

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