#carbene search results
Cyclic (Alkyl)(Amino)Carbene-Iminoboryl Compounds with Three Formal Oxidation States | Journal of the American Chemical Society @CHNSci #Carbene #IminoBoryl #OxidationStates @Boron_Chemistry pubs.acs.org/doi/10.1021/ja…
pubs.acs.org
Cyclic (Alkyl)(Amino)Carbene-Iminoboryl Compounds with Three Formal Oxidation States
BN/CC isosterism is an effective strategy to build hybrid functional molecules with unique properties. In contrast to the alkynyl iminium salts derived from cyclic (alkyl)(amino)carbenes (CAACs) that...
A Lead(II) Substituted Triplet Carbene | Journal of the American Chemical Society @Saar_Uni #Pb #Triplet #Carbene pubs.acs.org/doi/10.1021/ja…
![J_A_C_S's tweet card. Reaction of the pincer-type ligand L3 supported complex [L3PbBr][BArF24] (1) with Li[(C(═N2)TMS)] furnishes [L3Pb(C(═N2)TMS)][BArF24] (2). Diazo-compound 2 eliminates dinitrogen upon irradiation...](https://pbs.twimg.com/card_img/2046149287336140800/7REd6Qg0?format=jpg&name=orig)
Carbene-Assisted Arene Ring-Opening | Journal of the American Chemical Society @TotalSyntheses #Carbene #Arene #RingOpening pubs.acs.org/doi/10.1021/ja…
The Dynamic Lewis Acid–Carbene Hybrid: Pushing the Electrophilicity of Carbenes to the Limit | Journal of the American Chemical Society @CHNSci @TotalSyntheses #Dynamic #LewisAcid #Carbene #Electrophilicity pubs.acs.org/doi/10.1021/ja…
Iron(III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion | JACS @UniBasel @UniBasel_en @NarayanSinha01 @WengerOliver #Fe #Carbene #Tunable #ExcitedState #Energies #Photoredox #Upconversion pubs.acs.org/doi/10.1021/ja…
Construction of Ge-Stereogenic Center by Desymmetric Carbene Insertion of Dihydrogermanes | Journal of the American Chemical Society @CHNSci #Ge #StereogenicCenter #Carbene #Insertion #Dihydrogermane pubs.acs.org/doi/10.1021/ja…
Carbene-Stabilized Phosphagermylenylidene: A Heavier Analog of Isonitrile | Journal of the American Chemical Society #Carbene #Phosphagermylenylidene #Isonitrile pubs.acs.org/doi/10.1021/ja…
N-Heterocyclic Carbene-Derived Carbon Disulfide Radical Ligands for Palladium Diradicals | Journal of the American Chemical Society #NHC #Carbene #Disulfide #Radical #Ligands #Pd #Diradicals @TotalSyntheses pubs.acs.org/doi/10.1021/ja…
Cooperative Carbene Photocatalysis for β-Amino Ester Synthesis | Journal of the American Chemical Society @NUchemistry @NorthwesternU @karl_scheidt @TotalSyntheses #Cooperative #Carbene #Photocatalysis #AminoEster pubs.acs.org/doi/10.1021/ja…
Synthesis of Carbene-Stabilized PNPN Fragments and Their Carbene-Dependent Redox Properties | Journal of the American Chemical Society @uvic @chemistryatuvic @MannersResearch #Carbene #Redox #Properties pubs.acs.org/doi/10.1021/ja…
![J_A_C_S's tweet card. Herein, we report the synthesis of carbene-stabilized 1,3-diaza-2,4-diphosphabutenes CAACMePNPNCAACMe 4CAAC (CAACMe = 1-[2,6-bis(isopropyl)phenyl]-3,3,5,5-tetramethyl-2-pyrrolidinylidene) and...](https://pbs.twimg.com/card_img/2045380402450198528/6LpdHPwg?format=jpg&name=orig)
A bis-Phenolate Carbene-Supported bis-μ-Oxo Iron(IV/IV) Complex with a [FeIV(μ-O)2FeIV] Diamond Core Derived from Dioxygen Activation | Journal of the American Chemical Society @HumboldtUni @UniFAU #Phenolate #Carbene #OxoFe #Dioxygen #Activation pubs.acs.org/doi/10.1021/ja…
![J_A_C_S's tweet card. The diiron(II) complex, [(OCO)Fe(MeCN)]2 (1, MeCN = acetonitrile), supported by the bis-phenolate carbene pincer ligand, 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)benzimidazolin-2-ylidene (OCO), was...](https://pbs.twimg.com/card_img/2044761195077582848/Z4PcG_hy?format=jpg&name=orig)
Carbene Complexes of Plutonium: Structure, Bonding, and Divergent Reactivity to Lanthanide Analogs | Journal of the American Chemical Society @nfchilton @OfficialUoM @scienceANU @UoMChemistry @LosAlamosNatLab #Carbene #Plutonium #Ln #Reactivity pubs.acs.org/doi/10.1021/ja…
Dicationic Acridinium/Carbene Hybrids as Strongly Oxidizing Photocatalysts | Journal of the American Chemical Society @ckerzig @uni_mainz @MMHansmann_chem @TU_Dortmund #Dication #Acridinium #Carbene #Oxidizing #OrganoPhotocatalysts pubs.acs.org/doi/10.1021/ja…
Catalyst Control over S(IV)-stereogenicity via Carbene-derived Sulfinyl Azolium Intermediates | Journal of the American Chemical Society #Catalyst #Control #Carbene #Sulfinyl #Azolium @TotalSyntheses pubs.acs.org/doi/10.1021/ja…
Diaryldiazoketones as Effective Carbene Sources for Highly Selective Rh(II)-Catalyzed Intermolecular C–H Functionalization Journal of the American Chemical Society @EmoryUniversity @EmoryChem #Diazoketones #Carbene #Rh #CHFunctionalization @TotalSyntheses pubs.acs.org/doi/10.1021/ja…
Divergent Geminal Alkynylation–Allylation & Acylation–Allylation of Carbenes: Evolution & Roles of 2 Transition-Metal Catalysts | Journal of the American Chemical Society @CHNSci @TotalSyntheses #Alkynylation #Alkylation #Carbene #QuaternaryCenters #Cu #Rh pubs.acs.org/doi/10.1021/ja…
#A 67-year-old theory about vitamin B1 is confirmed as chemists stabilize a reactive #Carbene in water, paving the way for greener, more efficient pharmaceutical production. @UCRiverside @ScienceAdvances doi.org/g9f8df phys.org/news/2025-04-s…
Phosphine versus Carbene Metal Interactions: Bond Energies | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Dixon and co-workers @InorgChem #phosphine #carbene #DFT #CCSDT #LBEs #Group1 #Group2 #Group10 #Group11 #ionicradii #hardness
Carbene-Decorated Geometrically Constrained Borylenes for Bond Activations | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Fernández, Phukan, and co-workers @InorgChem #carbene #borylenes #activation #QuantumChemicalCalculations
#OpenAccess #Review 📑Title: Use of N-Heterocyclic #Carbene Compounds (NHCs) Under #Sustainable Conditions—An Update Authors: Abdelkarim El Qami et al. 📌 brnw.ch/21x1tDW
Enantioselective NHC/Cu-catalyzed dearomative cyclopropanation of indoles with diazo esters. ✔ up to 90% ee ✔ cyclopropane-fused indolines with quaternary stereocenters ✔ earth-abundant Cu catalysis 🔗 sciexplor.com/articles/cc.20… #AsymmetricCatalysis #Dearomatization #Carbene
Carbene Assisted Arene Ring-Opening pubs.acs.org/doi/10.1021/ja… #organic #synthesis #carbene #Organic_Chemistry
Delighted to share our latest @OrgLett publication: “A Quadruple Relay Approach Towards Highly Functionalized Furans.” 🔗 pubs.acs.org/doi/10.1021/ac… Congrats to all co-authors! @DrSharada_PU @PU_PondyUni #Carbene #PaalKnorr #Ruthenium #SemiPinacol #Serbonline #IndiaDST #UGC
Homoleptic Iridium(III) Carbene Complexes with gem-Dimethyl-1,2,4-triazolo[4,3-a]indole Chelates for Blue Organic Light-Emitting Diodes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Zhang, Chen, Wong, and co-workers @InorgChem #iridium #carbene #OLED
![bhkenlo's tweet image. Homoleptic Iridium(III) Carbene Complexes with gem-Dimethyl-1,2,4-triazolo[4,3-a]indole Chelates for Blue Organic Light-Emitting Diodes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Zhang, Chen, Wong, and co-workers @InorgChem #iridium #carbene #OLED](https://pbs.twimg.com/media/GwjydNWbYAAXqJq.png)
Synthesis, Structures, Photophysics, and Electroluminescence of Dinuclear Carbene-Au(I)-Amide Complexes Featuring the Through-Space Charge Transfer Excited State | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Li, Chen, and co-workers @InorgChem #gold #carbene #amide #NHC #EL #TADF
Impressive research on the synthesis of innovative #carbene-derived stable radicals by Eunsung Lee @EunsungLee5 @chemsnu. Presented at #PSRC11.
Scientists have synthesized a doubly oxidized carbene, a molecule with less than 8 electrons in its valence shell, defying the octet rule. This could pave the way for new chemical applications. #Chemistry #Carbene tinyurl.com/23sragfc
Super-shielded carbene is stable in liquid water: chemistryworld.com/news/super-shi… via @ChemistryWorld #UCRscience #carbene #water #chemistry #ucr #ucriverside
Carbene Assisted Arene Ring-Opening pubs.acs.org/doi/10.1021/ja… #organic #synthesis #carbene #Organic_Chemistry
#A 67-year-old theory about vitamin B1 is confirmed as chemists stabilize a reactive #Carbene in water, paving the way for greener, more efficient pharmaceutical production. @UCRiverside @ScienceAdvances doi.org/g9f8df phys.org/news/2025-04-s…
Agradecimientos a la Dra. Gloria Sánchez Cabrera, de la Universidad Autónoma del Estado de Hidalgo, quien impartió su interesante conferencia en el #EQI2025: "El viaje de la síntesis a la aplicación de carbenos metálicos NHC" #carbene #silver #gold #OrganometalllicChemistry
Peripheral-Carbazole-Group-Functionalized Tetradentate Carbene Platinum(II)/Palladium(II) Phosphorescent Complexes: Synthesis, Structures, and Optical Tuning | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Shi and co-workers @InorgChem #platinum #palladium #carbene #carbazole
Isolation and Reactivity of Carbene-Stabilized Carbon Disulfide Radical Anions | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Wilson, Machan @RJGilliard and co-workers @InorgChem #CAAC #carbene #CS2 #radical_anions
Stabilization of [(N5)2BX]2– and [(N5)2B2X2]2– (X = H, F, Cl, Br) by Conjugation and Hyperconjugation Effects | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Zhang, Schaefer III, and co-workers @InorgChem #boron #carbene #borylene #NBO #LOL #ELF #conjugation #hyperconjufation
![bhkenlo's tweet image. Stabilization of [(N5)2BX]2– and [(N5)2B2X2]2– (X = H, F, Cl, Br) by Conjugation and Hyperconjugation Effects | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Zhang, Schaefer III, and co-workers @InorgChem #boron #carbene #borylene #NBO #LOL #ELF #conjugation #hyperconjufation](https://pbs.twimg.com/media/GijkZOqa0AAY66A.png)
In just a decade, #hypervalent iodine and #carbene chemistry has exploded!💥New reactions, new reagents, and new possibilities. As highlighted by Ramirez @Nieves_P_R and Jerome Wasser (@LcsoLab), this field is constantly evolving. #OpenAccess Read more👉thieme-connect.de/products/ejour…
Low Temperature Emissive Cyclometalated Cobalt(III) Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Bauer and co-workers @InorgChem #cobalt #cyclometalated #carbene #emission #lowT #3MC #DFT
![bhkenlo's tweet card. A series of CoIII complexes [Co(RImP)2][PF6], with HMeImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazole-2-ylidene)) and R = Me, Et, iPr, nBu, is presented in this work. The influence of the strong...](https://pbs.twimg.com/card_img/2044761197476470784/C0_M2oD3?format=jpg&name=orig)
👉Don't miss this exciting research from Yuzhen Gao, Weiping Su et al. Remote C(sp3)–H acylation of amides under #photoredox cooperative N-heterocyclic #carbene/palladium catalysis doi.org/10.1039/D4QO01…
Au(I) complexes, #CrystalStructure , #MolecularDynamic Article by Prof. Hajime Ito @haj19932469 and Dr. Mingoo Jin @MingooJin @HokkaidoUni (Hokkaido University) #Carbene #Chemistry academic.oup.com/chemlett/artic…
Here is our latest article in @EurJIC @ChemEurope Dipicolinate-Ruthenium-NHC/trpy Complexes: Pincer Ligand Induced Hemilability of Dipicolinate and Enhancement of Cytotoxic Property. Again congratulations to @PapuDhibar2 #ruthenium #carbene #cytotoxicity …mistry-europe.onlinelibrary.wiley.com/doi/10.1002/ej…
Covalent #carbene modification of #2D #BlackPhosphorus. @2Dmaterials @ELSchemistry Read it: sciencedirect.com/science/articl…
N-heterocyclic carbene-catalyzed atroposelective synthesis of axially chiral 5-aryl 2-pyrones from enals @OrgSynth @Szostak_Group #nhc2022 #Carbene link.springer.com/article/10.100…
Half-sandwich iridium(III) benzimidazole-appended imidazolium-based N-heterocyclic #carbene complexes display good #antitumor activity doi.wiley.com/10.1002/asia.2…
Sabari Veerapathiran & Ganesan Prabusankar report simple and fast access to phosphine-substituted copper(I)-#carbene complexes via CSe #BondCleavage reaction. @gprabusankar @IITHyderabad onlinelibrary.wiley.com/doi/10.1002/as…
Online NOW | @J_A_C_S #Carbene-#Catalyzed #Enantioselective #Sulfonylation of Enone Aryl Aldehydes: A New Mode of Breslow Intermediate #Oxidation. @isciverse @AmerChemSociety #Chemistry pubs.acs.org/doi/10.1021/ja…
Carbene-Decorated Geometrically Constrained Borylenes for Bond Activations | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Fernández, Phukan, and co-workers @InorgChem #carbene #borylenes #activation #QuantumChemicalCalculations
Online NOW | @J_A_C_S 2H-Imidazol-2-one O-Oxide: A #Criegee Intermediate from a σ0π2 Singlet Ground-State #Carbene. @isciverse @AmerChemSociety #Chemistry pubs.acs.org/doi/10.1021/ja…
Utilization of a Tris(carbene)borate Ligand for Umpolung Reactivity of a Nucleophilic Tin(II) Cation Salt pubs.acs.org/doi/10.1021/ac… Hu and Liu @InorgChem #tin #carbene #borate #TCB #umpolung #σ_donating #π_accepting #coinage_metals #NBO #IBO #nucleophilicity
Rigidification-Induced Emissive Metal–Carbene Complexes for Artificial Light Harvesting | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Mukherjee and co-workers @InorgChem #silver #imidazolium #carbene #NHC #TPE #EosinY #rigidification
Planar-chiral #ferrocene-based N-heterocyclic #carbene ligands reviewed by Yoshida and Yasue #ChibaUni doi.wiley.com/10.1002/chem.2…
Sole, Fernandez et al. @UniBarcelona @isra_group report on a new method for synthesizing tetrahydroquinolines based on transition-metal-catalyzed intramolecular #carbene functionalization of diazoesters #HomogeneousCatalysis doi.wiley.com/10.1002/chem.2…
Peripheral-Carbazole-Group-Functionalized Tetradentate Carbene Platinum(II)/Palladium(II) Phosphorescent Complexes: Synthesis, Structures, and Optical Tuning | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Shi and co-workers @InorgChem #platinum #palladium #carbene #carbazole
Ever heard of acylation of a #C–H bond? Professor Studer´s group has an interest in N-heterocyclic #carbene (NHC) catalyzed radical transformations, which could offer a potential solution to the challenging issue posed by site-selective late C–H acylation👉fal.cn/3hHw6
[Accounts] N-Heterocyclic carbenes | Phosphine oxide | Frustrated lewis pairs Account by Dr. Yoichi Hoshimoto @Yhoshimoto and Prof. Sensuke Ogoshi @doytter (Osaka Univ.) is available as Open Access #NHeterocyclicCarbenes #Carbene #FrustratedLewisPair journal.csj.jp/doi/abs/10.124…
![CSJjournals_jp's tweet image. [Accounts]
N-Heterocyclic carbenes | Phosphine oxide | Frustrated lewis pairs
Account by Dr. Yoichi Hoshimoto @Yhoshimoto and Prof. Sensuke Ogoshi @doytter (Osaka Univ.) is available as Open Access
#NHeterocyclicCarbenes #Carbene #FrustratedLewisPair
journal.csj.jp/doi/abs/10.124…](https://pbs.twimg.com/media/E3ezhmWVEAQrKrM.jpg)
Synthesis, Structural Characterization, and Phosphorescence Properties of Trigonal Zn(II) Carbene Complexes | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Marian, @LabSteffen and co-workers @InorgChem #zinc #carbene #NHC #halides #atypical #DFT #MRCI #long_lived #low_coordinated
Thermally Activated Delayed Fluorescence Mechanism of a Bicyclic “Carbene–Metal–Amide” Copper Compound: DFT/MRCI Studies and Roles of Excited-State Structure Relaxation pubs.acs.org/doi/10.1021/ac… Gao, Cui, and co-workers @InorgChem ⭐️Featured Article⭐️ #copper #carbene #amide #TADF
Au(I) complexes, #CrystalStructure , #MolecularDynamic Article by Prof. Hajime Ito @haj19932469 and Dr. Mingoo Jin @MingooJin @HokkaidoUni (Hokkaido University) #Carbene #Chemistry academic.oup.com/chemlett/artic…
Stabilization of [(N5)2BX]2– and [(N5)2B2X2]2– (X = H, F, Cl, Br) by Conjugation and Hyperconjugation Effects | Inorganic Chemistry pubs.acs.org/doi/10.1021/ac… Zhang, Schaefer III, and co-workers @InorgChem #boron #carbene #borylene #NBO #LOL #ELF #conjugation #hyperconjufation
Efficient Nicotinamide Adenine Dinucleotide Regeneration with a Rhodium–Carbene Catalyst and Isolation of a Hydride Intermediate pubs.acs.org/doi/10.1021/ac… Park, Yoon, and co-workers @InorgChem 🌟Featured Article🌟 #rhodium #carbene #NADH #catalysis #MDI
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